摘要：本论文研究的是如何合成含氧化复合催化材料,以及催化醇类脱氢反应的各种性能。首先，需要制备的是氧化物复合催化材料，将它应用于醇类脱氢氧化的反应，以此来确定最佳路线及最佳合成反应需要的工艺条件。

本论文选择的对象是壳聚糖负载贵金属的催化剂、醇氧化脱氢反应。并且详细调研了它的催化剂发展历史并加以汇总。为了考察它们在醇氧化脱氢下的催化反应能力，自行调制了壳聚糖席夫碱钯催化剂还有以壳聚糖席夫碱钯催化剂负载的SiO2。

1壳聚糖席夫碱钯催化剂的制备和表征

 壳聚糖席夫碱钯催化剂的制备过程第一步用水杨醛接枝调制壳聚糖并且得到壳聚糖席夫碱，随后与PdCl2乙醇溶液调试得到壳聚糖席夫碱钯催化剂。壳聚糖席夫碱钯催化剂的表征需要用到诸多分析手段，例如：X-射线光电子能谱、荧光光谱、热重分析等。

2反应温度对催化性能的影响

3反应时间对催化性能的影响

4催化剂的用量对催化性能的影响

5催化剂稳定性

关键词:  壳聚糖;席夫碱;钯催化剂;醇氧化脱氢反应

 Preparation of alcohol selective oxidation catalyst

Abstract: In this paper, we have studied how to synthesize various catalytic properties of oxygenated composite materials and the various dehydrogenation reactions of alcohols. First, the oxide complex catalytic material needs to be prepared, which is applied to the reaction of alcohols dehydrogenation oxidation, in order to determine the optimum route and the optimum synthetic reaction process conditions.

In this thesis, the catalysts for the chitosan supported noble metals and the oxidative dehydrogenation of alcohols are selected. And detailed research on its catalyst development history and summary. In order to investigate their catalytic reaction ability under oxidative dehydrogenation of alcohol, the chitosan Schiff base palladium catalyst and SiO2 loaded with chitosan Schiff base palladium catalyst were self modulated.

1 Preparation and characterization of chitosan Schiff base palladium catalyst

The preparation of chitosan Schiff base palladium catalyst was first prepared by grafting chitosan and chitosan Schiff base with salicylaldehyde. The chitosan Schiff base palladium catalyst was then tested with PdCl2 ethanol solution. The characterization of chitosan Schiff base palladium catalyst requires many analytical methods, such as X- ray photoelectron spectroscopy, thermogravimetric analysis and fluorescence spectroscopy.

2 Effect of reaction temperature on catalytic performance

3 Effect of reaction time on catalytic performance

4 The amount of catalyst on the catalytic performance

5 Catalyst stability

Key words: chitosan; Schiff base; palladium catalyst; oxidative dehydrogenation of alcohols

目录

1. 绪论 1

1.1 本课题的意义、目的、研究范围 2

1.1.1 课题背景 2

1.1.2 课题的目的及意义 2

1.1.3 课题研究范围 3

2. 文献综述 4

2.1 钯催化剂 4

2.1.1 概述 4

2.1.2 物理性质 4

2.1.3 化学性质 4

2.1.4 主要用途 5

2.1.5 负载型钯催化剂 5

2.2 金属纳米颗粒概述 6

2.3 壳聚糖负载贵金属 6

2.3.1 概述 6

2.3.2 壳聚糖负载贵金属的制备方法及可能结构 7

2.3.3 壳聚糖负载贵金属的催化性能研究 9

2.4  1-苯乙醇 12

2.4.1 概述 12

2.4.2 性质与稳定性 12

2.4.3 应用 12

3. 壳聚糖席夫碱钯催化剂的制备与表征 13

3.1 仪器和试剂 13

3.1.1 试剂 13

3.1.2 仪器 13

3.2 催化剂的制备 13

3.2.1 壳聚糖席夫碱钯催化剂的制备和表征 13

3.2.2 Pd(0)催化剂催化前后红外光谱 20

3.2.3  XPS分析 21

3.2.4  热重分析 21

3.2.5 制备SiO2-CS 22